- The law was empirically discovered by Josef Stefan (1879) and theoretically derived by Ludwig Boltzmann (1884) using classical thermodynamics.
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The total energy radiated per unit surface area of a Black Body per unit time is proportional to the fourth power of its absolute temperature
$ j = \sigma T^4 $
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There is no material (yet) that is a Perfect Black Body (perfectly emit/absorb radiated power), thus the introduction of Emissivity into the equation.
$\epsilon $ -
New Formula (imposing the Real World)
$ j = \epsilon \sigma T^4 $
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$ \epsilon = 1 $
- A perfect black body (or absorber/emitter)
- Is able to equally emit and absorb the maximum possible thermal radiation at a given temperature
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$ \epsilon = 0 $
- A perfect white body (or reflector)
- Is able to reflect all incoming radiation perfectly
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$ 0 \leq \epsilon \leq 1 $
- Thus, emissivity of genuine, real world material should fall into this range.
- In SpaceX's Starship, the emissivity of the black tiles (that are a close perfect black body ~0.9
$\epsilon$ ) prevents heating the steel interior (shiny white body) as it radiates nearly 500 kilowatts of energy per square meter out and away into space- essentially it is really close to shedding as much heat as it takes.