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README.md

Carbon monoxide (2_CO)

This tutorial illustrates how to run a calculation for a zero-dimensional system (molecule/quantum-dot).
Follow the exercises from the sub-folders in numerical order.

Running the exercise

Enter each sub-directory in numerical order, and follow the detailed instructions in each README file.

  • 0_cutoff
    • Convergence with respect to the kinetic energy cutoff
  • 1_cellsize
    • Convergence with respect to the cell size (vacuum)
  • 2_relax
    • Compute the equilibrium bond length in the CO molecule
  • 3_binding
    • Compute the binding energy of the CO molecule
    • Understand how to treat orbital occupation correctly in an open shell, isolated atom
  • 3_HomoLumo
    • Visualize the HOMO and LUMO of the CO molecule
    • Investigate the orbital character as a function of cell size
  • 4_LennardJones
    • Use a Lennard-Jones like potential to fit the Energy vs Bond length curves
  • 4_dissociation
    • Investigate the dissociation of the CO molecule and fit to a Morse potential
  • 5_project_states
    • Project the molecular states onto atomic orbitals
  • OLD_0_cellsize
    • Run a relax calculation for a molecule and visualize the output using xcrysden
    • Plot the electrostatic potential in the cell
    • Converge the bond length with the cell size
    • Test convergence of other properties with cell size
  • OLD_2_relax
    • Converge the geometry with the kinetic energy cutoff