I have tried to set PATH to linux_for_riscv_em/output_mmu_rv32/buildroot/output/host/bin/, I built the Linux kernel and it runs successfully in your emulator.
I think buildroot has built the toolchain already, so there is no need to download your pre-built binaries from https://github.com/franzflasch/gcc-build-tools. Should we mention this in the README?