If you leave the SIDKick Pico on umodified default settings (8580) then samples won't play correctly.
For example this SID has no samples:
https://csdb.dk/release/?id=13863
I can't test it right now, but I believe that also the title music of Bad Cat had problems with the samples (normally they have a low volume on the 8580, but in the SIDKick Pico emulation they are missing completely).
If you leave the SIDKick Pico on umodified default settings (8580) then samples won't play correctly.
For example this SID has no samples:
https://csdb.dk/release/?id=13863
I can't test it right now, but I believe that also the title music of Bad Cat had problems with the samples (normally they have a low volume on the 8580, but in the SIDKick Pico emulation they are missing completely).