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| 1 | +@prefix CHEBI: <http://purl.obolibrary.org/obo/CHEBI_> . |
| 2 | +@prefix OBI: <http://purl.obolibrary.org/obo/OBI_> . |
| 3 | +@prefix SIO: <http://semanticscience.org/resource/SIO_> . |
| 4 | +@prefix VOC4CAT: <https://w3id.org/nfdi4cat/voc4cat_> . |
| 5 | +@prefix coremeta4cat: <https://w3id.org/nfdi4cat/coremeta4cat/> . |
| 6 | +@prefix dcat: <http://www.w3.org/ns/dcat#> . |
| 7 | +@prefix dcterms: <http://purl.org/dc/terms/> . |
| 8 | +@prefix prov: <http://www.w3.org/ns/prov#> . |
| 9 | +@prefix qudt: <http://qudt.org/schema/qudt/> . |
| 10 | +@prefix xsd: <http://www.w3.org/2001/XMLSchema#> . |
| 11 | + |
| 12 | +coremeta4cat:DS_001_MeOH_synthesis_CuZnO a dcat:Dataset ; |
| 13 | + dcterms:description "Dataset covering preparation of Cu/ZnO/Al2O3 methanol synthesis catalyst by incipient wetness impregnation and catalytic performance in CO2 hydrogenation at 50 bar, 200-300 deg C." ; |
| 14 | + dcterms:subject coremeta4cat:CAT_001_CuZnO_Al2O3 ; |
| 15 | + dcterms:title "Methanol synthesis over Cu/ZnO/Al2O3: synthesis and catalytic performance dataset" ; |
| 16 | + prov:wasGeneratedBy coremeta4cat:CHAR_001_BET_CuZnO_Al2O3, |
| 17 | + coremeta4cat:CHAR_002_XRD_CuZnO_Al2O3, |
| 18 | + coremeta4cat:SYNTH_001_Pt_Al2O3 . |
| 19 | + |
| 20 | +<https://pubchem.ncbi.nlm.nih.gov/compound/962> a CHEBI:23367 ; |
| 21 | + dcterms:title "deionized water" . |
| 22 | + |
| 23 | +coremeta4cat:CHAR_001_BET_CuZnO_Al2O3 a "Characterization" ; |
| 24 | + prov:used coremeta4cat:CAT_001_CuZnO_Al2O3, |
| 25 | + coremeta4cat:CHAR_001_BET_method ; |
| 26 | + prov:wasAssociatedWith coremeta4cat:DEV_001_Micromeritics_ASAP2020 . |
| 27 | + |
| 28 | +coremeta4cat:CHAR_001_BET_method a OBI:0000272 ; |
| 29 | + dcterms:description "N2 physisorption at 77 K, degassing at 300 deg C for 3 h under vacuum prior to measurement" ; |
| 30 | + dcterms:title "BET surface area measurement" . |
| 31 | + |
| 32 | +coremeta4cat:CHAR_002_XRD_CuZnO_Al2O3 a "Characterization" ; |
| 33 | + prov:used coremeta4cat:CAT_001_CuZnO_Al2O3, |
| 34 | + coremeta4cat:CHAR_002_XRD_method ; |
| 35 | + prov:wasAssociatedWith coremeta4cat:DEV_002_Bruker_D8_Advance . |
| 36 | + |
| 37 | +coremeta4cat:CHAR_002_XRD_method a OBI:0000272 ; |
| 38 | + dcterms:description "Cu K-alpha, 2theta range 5 to 80 deg, step size 0.02 deg, scan rate 1 deg/min, Rietveld refinement for phase quantification" ; |
| 39 | + dcterms:title "powder X-ray diffraction" . |
| 40 | + |
| 41 | +coremeta4cat:DEV_001_Micromeritics_ASAP2020 a prov:Agent ; |
| 42 | + dcterms:title "Micromeritics ASAP 2020 surface area and porosimetry analyzer" . |
| 43 | + |
| 44 | +coremeta4cat:DEV_002_Bruker_D8_Advance a prov:Agent ; |
| 45 | + dcterms:title "Bruker D8 Advance diffractometer with Cu K-alpha radiation (1.5406 Ang)" . |
| 46 | + |
| 47 | +coremeta4cat:PREC_001_H2PtCl6 a VOC4CAT:0007794 ; |
| 48 | + dcterms:title "chloroplatinic acid hexahydrate" ; |
| 49 | + VOC4CAT:0008118 [ a qudt:Quantity ; |
| 50 | + qudt:hasQuantityKind <http://qudt.org/vocab/quantitykind/Mass> ; |
| 51 | + qudt:unit <https://qudt.org/vocab/unit/GM> ; |
| 52 | + prov:value "0.0485"^^xsd:float ] . |
| 53 | + |
| 54 | +coremeta4cat:SYNTH_001_Pt_Al2O3 a "Synthesis" ; |
| 55 | + SIO:000008 [ a VOC4CAT:0000122 ; |
| 56 | + prov:value "reduction in H2 at 400 deg C for 2 hours prior to catalytic testing" ] ; |
| 57 | + prov:used coremeta4cat:PREC_001_H2PtCl6, |
| 58 | + coremeta4cat:SYNTH_001_impregnation_method ; |
| 59 | + coremeta4cat:catalyst_measured_properties "BET surface area: 185 m2/g, Pt particle size: 2.3 nm (TEM), Pt loading: 4.8 wt% (ICP-AES)" ; |
| 60 | + coremeta4cat:nominal_composition "5 wt% Pt/Al2O3" ; |
| 61 | + VOC4CAT:0007246 <https://pubchem.ncbi.nlm.nih.gov/compound/962> ; |
| 62 | + VOC4CAT:0008104 "gamma-Al2O3, Sasol Puralox, 200 m2/g" ; |
| 63 | + VOC4CAT:0008105 "stored in desiccator under argon atmosphere at room temperature" . |
| 64 | + |
| 65 | +coremeta4cat:SYNTH_001_impregnation_method a VOC4CAT:0007016 ; |
| 66 | + dcterms:description "incipient_wetness, 25 deg C, 12 h" ; |
| 67 | + dcterms:title "incipient wetness impregnation" . |
| 68 | + |
| 69 | +coremeta4cat:CAT_001_CuZnO_Al2O3 a prov:Entity ; |
| 70 | + dcterms:description "63 wt% CuO, 24 wt% ZnO, 13 wt% Al2O3 (calcined precursor)" ; |
| 71 | + dcterms:title "Cu/ZnO/Al2O3 methanol synthesis catalyst" . |
| 72 | + |
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