@@ -14,7 +14,7 @@ Calculations of X-ray properties of materials
1414
1515This section presents several detailed examples of using
1616`xraydb.sqlite ` to calculate X-ray properties of materials. All of
17- the examples here us the functions in the python `xraydb ` module,
17+ the examples here use the functions in the python `xraydb ` module,
1818which is describe in more detail in the next chapter,
1919:ref: `python_api `. The examples will explore some aspects of X-ray
2020physics, but will not give a complete tutorial on the concepts here.
@@ -34,7 +34,7 @@ photo-electric effect is the main process that causes X-ray attenuation.
3434When the photo-electric process is dominant, the values for
3535:math: `\mu /\rho ` depends strongly on *Z * of the atom and on X-ray energy
3636*E *. In addition to these strong dependencies, sharp increases --
37- so-called absorption edges -- with be see at energies of bound core
37+ so-called absorption edges -- with be seen at energies of bound core
3838electron levels of atoms. To illustrate these characteristics, the
3939following script will plot :math: `\mu /\rho ` for selected elements:
4040
@@ -55,7 +55,7 @@ depends strongly with *Z*, though the sharp absorption edges make this more
5555complicated.
5656
5757You can also observe that at relatively high energies for relatively low-Z
58- elements (such as C above about 20 keV) that the attenuation levels off.
58+ elements (such as C above about 20 keV) the attenuation levels off.
5959This is because the coherent (Rayleigh) and incoherent (Compton) scattering
6060processes dominate, so that the photo-electric absorption is no longer the
6161dominant X-ray scattering process. This can be illustrated by plotting the
@@ -106,8 +106,8 @@ energy value and density (which are known for several common materials).
106106This gives the length for which X-ray intensity is reduced by a factor of
107107*e *, and so can be used to calculate the fraction of the X-rays transmitted
108108through a material of known thickness, as :math: `\exp (-t\mu )` for a
109- material of thickness *t *. As a first example, we calculate the the
110- fraction of X-ray transmitted through 1 mm of the water as a function of
109+ material of thickness *t *. As a first example, we calculate the
110+ fraction of X-ray transmitted through 1 mm of water as a function of
111111X-ray energy:
112112
113113.. literalinclude :: ../python/examples/mu_water.py
@@ -142,7 +142,7 @@ would generate the following plot
142142 Fraction of X-rays absorbed and transmitted by calcite
143143
144144
145- For many X-ray experiments, selecting the size of a material size so that
145+ For many X-ray experiments, selecting the size of a material so that
146146its thickness is approximately 1 to 2 absorption length is convenient so
147147that X-ray scattering and emission can be observed strongly, with neither
148148all primary and scattered X-rays being absorbed by the material itself, but
@@ -230,13 +230,13 @@ Ionization Potentials <xray_ionpot_table>`.
230230
231231From this table, we can see that the absorption (by photo-electric effect) of 1
232232X-ray with energy 10 keV will generate about 300 electron-ion pairs. That is
233- not much current, but if :math: `10 ^8 \,\rm Hz` X-rays are absorbed per second,
233+ not much current, but if :math: `10 ^8 \,\rm Hz` X-rays are absorbed ( per second) ,
234234then the current generated will be around 5 nA. Of course, the length of the
235235gas or more precisely the length of gas under ionizing potential will have an
236236impact on how much current is generated. The photo-current generated can be
237237amplified and converted to a voltage using a current amplifier, and that
238238voltage will then recorded by a number of possible mean: a voltage-to-frequency
239- generator and a digital counter is a common method for integrated current for a
239+ generator together with a digital counter is a common method for integrated current for a
240240specific amount of time, but other sampling methods can also be used.
241241
242242An ion chamber can be linear over many orders of magnitude of X-ray flux,
@@ -291,7 +291,7 @@ degrees will be
291291
292292 (recall that :math: `1 - 1 /(1 +x) = 1 / (1 +1 /x)`). For X-rays of 10 keV,
293293:math: `E_{\rm median}` is about 192 eV. For 20 keV X-rays, it will be 750 eV,
294- and for 50 keV X-rays, it will be 4.5 keV. Because of the angular distribution
294+ and for 50 keV X-rays, it will be 4.5 keV. Because the angular distribution
295295of Compton scattering is not uniform, these median values over-estimate the
296296amount of energy transferred to the scattered electron by a small amount that
297297increases with energy. The mean energy of the Compton-scattered electron can
@@ -440,7 +440,7 @@ X-ray energy and the incoherent cross-section with the ***mean***
440440Compton-scattering energy, using the calculated and tabulated mean energies of
441441the Compton-scattered electrons are used to estimate the incident flux from
442442the photo-current. The total attenuation cross-section, including the coherent
443- cross-sections, is used to calculate the transmitted flu from the incident
443+ cross-sections, is used to calculate the transmitted flux from the incident
444444flux.
445445
446446As an example calculation of ion chamber currents::
@@ -511,8 +511,8 @@ takes a list of materials from top to bottom, a matching list of
511511thicknesses of each layer, substrate material, incident angle, energy,
512512and the number of periods.
513513
514- An example usage, calculating the reflectivity at 1000 eV vs. grazing
515- angle for a 40*[Si, W] layered mirror on SiO2 substrate is given as
514+ An example usage, calculating the reflectivity at a grazing angle of 10 mrad
515+ vs. energy for a 40*[Si, W] layered mirror on SiO2 substrate is given as
516516
517517.. literalinclude :: ../python/examples/mirror_multilayer.py
518518
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