This paper derives a nonlinear fourteen-moment electron closure for rarefied, nonmagnetized, partially ionized plasmas where strong fields and finite electron drift invalidate linearized transport theory. A Hermitian velocity-distribution expansion evolves density, momentum, the anisotropic pressure tensor, contracted heat flux, and scalar kurtosis. Collision moments are integrated analytically at finite Mach number for elastic and inelastic electron-neutral interactions, electron-impact ionization, and electron-electron and electron-ion Coulomb collisions. The resulting terms couple moments of different tensorial rank, breaking the linear-regime Curie symmetry; examples include pressure-anisotropy effects on momentum and inelastic rates and kurtosis effects on heat-flux relaxation. In homogeneous argon calculations over
- Formulated a nonlinear 14-moment model for density, velocity, anisotropic pressure, heat flux, and scalar kurtosis.
- Integrated finite-drift nonlinear collision moments analytically for elastic, inelastic, ionization, and Coulomb processes.
- Identified cross-tensorial collisional couplings absent from linear closures.
- Quantified large anisotropy- and kurtosis-dependent corrections to collision rates.
- Demonstrated substantially better agreement with Monte Carlo kinetics than linear closures through
$1000$ Td.