DOC - Update link to User help guides for correct path

[leighghunt]

Description

Just a doc fix, making relative URL absolute.

Manual testing steps

Issues

• DOC - broken link to docs/en/userguide/index.md in docs/en/index.md #1425

Pull request checklist

• The target branch is correct
  • See picking the right version
• All commits are relevant to the purpose of the PR (e.g. no debug statements, unrelated refactoring, or arbitrary linting)
  • Small amounts of additional linting are usually okay, but if it makes it hard to concentrate on the relevant changes, ask for the unrelated changes to be reverted, and submitted as a separate PR.
• The commit messages follow our commit message guidelines
• The PR follows our contribution guidelines
• Code changes follow our coding conventions
• This change is covered with tests (or tests aren't necessary for this change)
• Any relevant User Help/Developer documentation is updated; for impactful changes, information is added to the changelog for the intended release
• CI is green